Just from the color sample panels I have here is some info. I'm still a newbie in PCing as well, but hope this bit of info helps. Yes it is noraml to have to do a 2 coat process for "most" of the fluorescent colors. You have 2 kinds of fluorescent colors the 1 coat process and the 2 coat process. The one coat fluorescent colors don't look near as bright, well I know you can tell big difference in the yellow one and yellow two coat. For the fluorescent 2 coat I believe its always a "white basecoat" then the fluorescent color on top of it.
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