Nah, don't do that, let's learn together..
I will be concentrating on castings too. I have done quite a bit of research, and there is work being done here in NZ on de-smut systems that will allow castings to be anodised more effectively. This is cutting-edge stuff that is still a bit secret at the moment, but it is happening (although that is all I know about it).
You might also be interested in this:
Quote:
Experience has shown that desmutting is one of the most critical steps in the aluminum pretreatment process. Historically, nitric acid solutions, with acid concentrations of 25% to 70%, have performed well to desmut etched aluminum alloys. Not all smut is easily removed with nitric acid alone, thus often additions of other components are made to improve the effectiveness of the desmut. For instance, for aluminum alloys containing high concentrations of silicon (e.g., 356A and 380 series cast alloys), additions of fluoride-containing compounds such as ammonium bifluoride or sodium fluoride, have been added such that fluoride ions are available to dissolve and remove silicon from the surface. Alternatively, a solution of nitric acid, sulfuric acid and a fluoride-containing salt has gained popularity over the years, because of its ability to chemically attack and remove a wider variety of metallic smuts.
[0008] While nitric acid has been very effective for desmutting etched aluminum, there has been increased resistance to its use because of safety and health concerns. For instance, development of toxic NO.sub.x fumes in nitric acid-containing baths has been of particular concern. To obviate this concern, there has been significant effort to develop and use non-nitric acid containing desmuts. One such approach has employed the use of chromic acid as the oxidant, again combined with sulfuric acid and a fluoride containing salt. This approach was successful for desmutting and avoids NO.sub.x concerns. However, the use of chromic acid brings with it toxicity concerns of its own.
[0009] An object of the present invention is to provide a composition that is free of acids such as nitric acid and chromic acid, thus eliminating the health, safety, and environmental concerns associated with these acids, but which is capable of being highly effective in its desmutting ability.
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(from
http://www.freshpatents.com/Nitric-a...0040242449.php )
There follows a highly technical (but interesting) discussion of what it does, and in the examples we find this:
Quote:
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[0045] Samples of cast aluminum alloy 356 and wrought aluminum alloys 2024 and 6061 are cleaned/degreased as described above followed by etching in Alklean AC-2. The etched samples are then immersed in the aqueous composition of Example A, and the ability to remove smut is evaluated. The cleaned samples are then processed through zincate steps followed by electroless nickel plating with Nichem-2500. The desmutting action of a fresh solution of Example A is Good, and the aged solution (after continuous use for three weeks is Fair/Poor. The adhesion of the plated nickel in the 90.degree. bend test to all three alloy samples is Good.
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So what I am saying is, there is hope for anodising castings. And this is public research.
I'm a bit of a rotor-head too...