I use 50/50, with a rosin core. Acid core is too tough on the substrate. The hardest part is knowing how to match the diameter to the task at hand. Lead free is a good approach but in all practicality it's difficult to work with. I've used the lead free that Caswell sells and have great luck with it now, but I've got a lot of filling under my belt.
If the copper is free of oxidation, you can go direct with the soldering, but if it's all dark, you want to just give it a rub with a scotchbrite. You can't put more than a few minutes of copper on the parts, so nothing too aggressive (same reason you can't use acid core).
Don't be too concerned about the melting point. Zinc's is a 700 or so, and solder is usually below that by a couple hundred degrees. I've also used a pure cadmium fill rod which is really low in temp and can be used direct on the pot metal.
I don't want to put things on a pedestal, but it's an art form to get solder to work well. Practice now on scrap. Not only depositing the solder, but see how it reacts when you sand it, and lightly sand blast it to, as you'll have to do that on the real piece, and it's real easy to get voids and so on in the solder that turn out to be a bear down the road if you miss them now.



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